N-Allylaniline (aa) can act as a uni- or bi-dentate ligand in complexes of composition [PdCl2(aa)2] affording an orange-yellow (1) and a dark red isomer (2). The palladium in (1) is four-co-ordinate and planar, with the olefin group unbound in benzene and dimethyl sulphoxide (dmso) solution. The olefin groups in (2) are bound to the palladium, which, in solution (NN-dimethylformamide, dmso, or acetone), is at least five-co-ordinate. Both complexes lose methylacetylene and allene to form trans-[PdCl2(NPhH2)2] on standing in the solid state or in solution. Isomer (1) requires elevated temperatures and long reaction times, but (2) decomposes readily at room temperature

Metal complexes of N-allylaniline. A palladium(II) complex with co-ordination number of greater than four / Aresta, M.; Nobile, C. F.; Petruzzelli, D.; Tobe, M. L.. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - STAMPA. - 5(1977), pp. 493-496. [10.1039/DT9770000493]

Metal complexes of N-allylaniline. A palladium(II) complex with co-ordination number of greater than four

Nobile, C. F.;Petruzzelli, D.;
1977-01-01

Abstract

N-Allylaniline (aa) can act as a uni- or bi-dentate ligand in complexes of composition [PdCl2(aa)2] affording an orange-yellow (1) and a dark red isomer (2). The palladium in (1) is four-co-ordinate and planar, with the olefin group unbound in benzene and dimethyl sulphoxide (dmso) solution. The olefin groups in (2) are bound to the palladium, which, in solution (NN-dimethylformamide, dmso, or acetone), is at least five-co-ordinate. Both complexes lose methylacetylene and allene to form trans-[PdCl2(NPhH2)2] on standing in the solid state or in solution. Isomer (1) requires elevated temperatures and long reaction times, but (2) decomposes readily at room temperature
1977
Metal complexes of N-allylaniline. A palladium(II) complex with co-ordination number of greater than four / Aresta, M.; Nobile, C. F.; Petruzzelli, D.; Tobe, M. L.. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - STAMPA. - 5(1977), pp. 493-496. [10.1039/DT9770000493]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11589/10234
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