The polymer-supported Fe(III) complex obtained by copolymerization of Fe(AAEMA)(3) [AAEMA(-) = deprotonated form of 2-(acetoacetoxy) ethyl methacrylate] with suitable acrylamides facilitates the coupling reaction between acyl chlorides and Grignard reagents, affording ketones with yields up to 96%. (C) 2000 Elsevier Science B.V. All rights reserved.
Coupling reactions between acyl chlorides and Grignard reagents in the presence of a supported Fe(III)-complex / Dell'Anna, Maria Michela; Mastrorilli, Piero; Nobile, Cosimo F.; Marchese, Giuseppe; Rosaria Taurino, Maria. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - STAMPA. - 161:1-2(2000), pp. 239-243. [10.1016/S1381-1169(00)00268-5]
Coupling reactions between acyl chlorides and Grignard reagents in the presence of a supported Fe(III)-complex
Maria Michela Dell'Anna;Piero Mastrorilli;Cosimo F. Nobile;
2000-01-01
Abstract
The polymer-supported Fe(III) complex obtained by copolymerization of Fe(AAEMA)(3) [AAEMA(-) = deprotonated form of 2-(acetoacetoxy) ethyl methacrylate] with suitable acrylamides facilitates the coupling reaction between acyl chlorides and Grignard reagents, affording ketones with yields up to 96%. (C) 2000 Elsevier Science B.V. All rights reserved.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
