A polypodal ligand based on an aromatic ring decorated by four dppa-type diphosphine moieties has been used to prepare Pt(ii) complexes and to assemble four tricobalt or tetracobalt carbonyl clusters, leading to centrosymmetric Co12 and Co16 «clusters of clusters» which were characterized by X-ray diffraction
Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co12 and Co16 branched clusters / Rodriguez Zubiri, M.; Gallo, Vito; Rosé, J.; Welter, R.; Braunstein, P.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 1(2008), pp. 64-66. [10.1039/b713540h]
Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co12 and Co16 branched clusters
GALLO, Vito;
2008-01-01
Abstract
A polypodal ligand based on an aromatic ring decorated by four dppa-type diphosphine moieties has been used to prepare Pt(ii) complexes and to assemble four tricobalt or tetracobalt carbonyl clusters, leading to centrosymmetric Co12 and Co16 «clusters of clusters» which were characterized by X-ray diffractionI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
