Exposure of solid trans-[Pt(PHCy2)(2)(PCy2)Cl] (1) to dry oxygen unexpectedly leads to [PtCl(PHCy2){(PCy2O)(2)H}] (2) as the major product, the formation of which has been followed by NOESY H-1 NMR techniques.
PtCl(PHCy2){(PCy2O)2H}: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complex / Mastrorilli, P.; Latronico, M.; Nobile, C. F.; Suranna, G. P.; Fanizzi, F. P.; Englert, U.; Ciccarella, G.. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - STAMPA. - 8(2004), pp. 1117-1119. [10.1039/b402180k]
PtCl(PHCy2){(PCy2O)2H}: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complex
Mastrorilli, P.;Latronico, M.;Nobile, C. F.;Suranna, G. P.;
2004-01-01
Abstract
Exposure of solid trans-[Pt(PHCy2)(2)(PCy2)Cl] (1) to dry oxygen unexpectedly leads to [PtCl(PHCy2){(PCy2O)(2)H}] (2) as the major product, the formation of which has been followed by NOESY H-1 NMR techniques.File in questo prodotto:
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