Dissociation and stability constants for protolytic and complex formation equilibria of a polyfunctional ligand are determined. Deprotonation is monitored by NMR controlled titrations. Macroscopic and microscopic concepts are discussed. Nickel complexes are more stable than those of Ca and Mg.
Pyridin-2-yl-(i-propylamino)-methane phosphonic acid -protonation and metal complex formation - NMR-controlled titration / Bier, A.; Failla, S.; Finocchiaro, P.; Hägele, G.; Latronico, M.; Libertini, E.; Ollig, J.. - In: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. - ISSN 1042-6507. - STAMPA. - 155:(1999), pp. 89-100. [10.1080/10426509908044973]
Pyridin-2-yl-(i-propylamino)-methane phosphonic acid -protonation and metal complex formation - NMR-controlled titration
Latronico, M.;
1999-01-01
Abstract
Dissociation and stability constants for protolytic and complex formation equilibria of a polyfunctional ligand are determined. Deprotonation is monitored by NMR controlled titrations. Macroscopic and microscopic concepts are discussed. Nickel complexes are more stable than those of Ca and Mg.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
