The reaction between Ni(0) complexes (dp) (dp = 1,2-bis(dicyclohexylphosphino)ethane, 1,3-bis(dicyclohexylphosphino)propane, 1,4-bis(dicyclohexylphosphino)butane; dcpe, dcpp, dcpb, respectively) and carbon dioxide is described. The influence of the PNiP bond angle on the stability of the corresponding adducts is discussed. The reactions of Ni(dcpp)CO2 and Ni(dcpb)CO2 with dioxygen are also described.

Carbon dioxide-transition metal complexes. IV. New Ni(0)CO2 complexes with chelating diphosphines: influence of PNiP angle on complex stabilities / Mastrorilli, Pietro; Moro, Giovanni; Nobile, Cosimo Francesco; Latronico, Mario. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 192:2(1992), pp. 189-193. [10.1016/S0020-1693(00)80758-6]

Carbon dioxide-transition metal complexes. IV. New Ni(0)CO2 complexes with chelating diphosphines: influence of PNiP angle on complex stabilities

Pietro Mastrorilli;Cosimo Francesco Nobile;Mario Latronico
1992-01-01

Abstract

The reaction between Ni(0) complexes (dp) (dp = 1,2-bis(dicyclohexylphosphino)ethane, 1,3-bis(dicyclohexylphosphino)propane, 1,4-bis(dicyclohexylphosphino)butane; dcpe, dcpp, dcpb, respectively) and carbon dioxide is described. The influence of the PNiP bond angle on the stability of the corresponding adducts is discussed. The reactions of Ni(dcpp)CO2 and Ni(dcpb)CO2 with dioxygen are also described.
1992
Carbon dioxide-transition metal complexes. IV. New Ni(0)CO2 complexes with chelating diphosphines: influence of PNiP angle on complex stabilities / Mastrorilli, Pietro; Moro, Giovanni; Nobile, Cosimo Francesco; Latronico, Mario. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 192:2(1992), pp. 189-193. [10.1016/S0020-1693(00)80758-6]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11589/570
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