The oxidation of benzylic and secondary alcohols under homogeneous conditions was achieved at 40°C using molecular oxygen as the oxidant in the presence of excess 2-methylpropanal and catalytic amount of Co(acac)2. The oxidation reactions were also carried out with a heterogeneous analogue of Co(acac)2 revealing that the supported cobalt polymer acts as an active and reusable catalyst.
Homogeneous and heterogeneous catalytic oxidation of benzylic and secondary alcohols with a metal dioxygenato complex in the presence of 2-methylpropanal and dioxygen / Roberta Cicco, Stefania; Latronico, Mario; Mastrorilli, Piero; Suranna, Gian Paolo; Nobile, Cosimo Francesco. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - STAMPA. - 165:1-2(2001), pp. 135-140. [10.1016/S1381-1169(00)00370-8]
Homogeneous and heterogeneous catalytic oxidation of benzylic and secondary alcohols with a metal dioxygenato complex in the presence of 2-methylpropanal and dioxygen
Mario Latronico;Piero Mastrorilli;Gian Paolo Suranna;Cosimo Francesco Nobile
2001-01-01
Abstract
The oxidation of benzylic and secondary alcohols under homogeneous conditions was achieved at 40°C using molecular oxygen as the oxidant in the presence of excess 2-methylpropanal and catalytic amount of Co(acac)2. The oxidation reactions were also carried out with a heterogeneous analogue of Co(acac)2 revealing that the supported cobalt polymer acts as an active and reusable catalyst.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
