This article reports the use of a cascade Suzuki–Heck reaction for the polymerization of suitable aryldibromides with potassium vinyltrifluoroborate resulting in the synthesis of a series of poly(fluorenylenevinylene)s. The protocol is characterized by a great versatility, deriving from the use of easily attainable substrates, and yields polymers with low percentages of structural 1,1-diarylenevinylene defects.

A novel synthetic protocol for poly(fluorenylenevinylene)s: a cascade Suzuki-Heck reaction / Grisorio, R.; Mastrorilli, P.; Nobile, C. F.; Romanazzi, G.; Suranna, G. P.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 46:15(2005), pp. 2555-2558. [10.1016/j.tetlet.2005.02.090]

A novel synthetic protocol for poly(fluorenylenevinylene)s: a cascade Suzuki-Heck reaction

Grisorio, R.;Mastrorilli, P.;Romanazzi, G.;Suranna, G. P.
2005-01-01

Abstract

This article reports the use of a cascade Suzuki–Heck reaction for the polymerization of suitable aryldibromides with potassium vinyltrifluoroborate resulting in the synthesis of a series of poly(fluorenylenevinylene)s. The protocol is characterized by a great versatility, deriving from the use of easily attainable substrates, and yields polymers with low percentages of structural 1,1-diarylenevinylene defects.
2005
A novel synthetic protocol for poly(fluorenylenevinylene)s: a cascade Suzuki-Heck reaction / Grisorio, R.; Mastrorilli, P.; Nobile, C. F.; Romanazzi, G.; Suranna, G. P.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 46:15(2005), pp. 2555-2558. [10.1016/j.tetlet.2005.02.090]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11589/6202
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