trans-PtCl2(PHBut2)21 reacts with NaBH4 in THF affording the dinuclear platinum(II) complexes cis-Pt2(H)2(PHBut2)2(μ-H)(μ-PBut2) (Pt–Pt) 2 and trans-[Pt(H)(PHBut2)(μ-PBut2)]2 (Pt–Pt) 3 along with the boron adduct BH3·PHBut24. Pure 2 can be obtained in 85% yield in the reaction carried out in the presence of two equivalents of di-tert-butylphosphine.

Synthesis and characterization of the neutral dinuclear hydrido complexes of platinum with bridging phosphides cis-Pt2(H)2(PHBut2)2(μ-H)(μ-PBut2) (Pt–Pt) and trans-[Pt(H)(PHBut2)(μ-PBut2)]2 (Pt–Pt) / Mastrorilli, Piero; Palma, Mariangela; Paolo Fanizzi, Francesco; Nobile, Cosimo Francesco. - In: DALTON. - ISSN 1470-479X. - STAMPA. - 23:(2000), pp. 4271-4276. [10.1039/b006341j]

Synthesis and characterization of the neutral dinuclear hydrido complexes of platinum with bridging phosphides cis-Pt2(H)2(PHBut2)2(μ-H)(μ-PBut2) (Pt–Pt) and trans-[Pt(H)(PHBut2)(μ-PBut2)]2 (Pt–Pt)

Piero Mastrorilli;Cosimo Francesco Nobile
2000-01-01

Abstract

trans-PtCl2(PHBut2)21 reacts with NaBH4 in THF affording the dinuclear platinum(II) complexes cis-Pt2(H)2(PHBut2)2(μ-H)(μ-PBut2) (Pt–Pt) 2 and trans-[Pt(H)(PHBut2)(μ-PBut2)]2 (Pt–Pt) 3 along with the boron adduct BH3·PHBut24. Pure 2 can be obtained in 85% yield in the reaction carried out in the presence of two equivalents of di-tert-butylphosphine.
2000
Synthesis and characterization of the neutral dinuclear hydrido complexes of platinum with bridging phosphides cis-Pt2(H)2(PHBut2)2(μ-H)(μ-PBut2) (Pt–Pt) and trans-[Pt(H)(PHBut2)(μ-PBut2)]2 (Pt–Pt) / Mastrorilli, Piero; Palma, Mariangela; Paolo Fanizzi, Francesco; Nobile, Cosimo Francesco. - In: DALTON. - ISSN 1470-479X. - STAMPA. - 23:(2000), pp. 4271-4276. [10.1039/b006341j]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11589/8519
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