In this work we report a new synthetic tactic for the straightforward preparation of hardly accessible sulfinamidines and sulfinamide esters, by using a simple metal-free protocol. The process is robust and uses readily available sulfenamides as the S-donor and sulfonyloxycarbamates as the N-source. The scope and mechanism have also been investigated.
Synthesis of Sulfinamidines and Sulfinimidate Esters by Transfer of Nitrogen to Sulfenamides / Andresini, Michael; Spennacchio, Mauro; Romanazzi, Giuseppe; Ciriaco, Fulvio; Clarkson, Guy; Degennaro, Leonardo; Luisi, Renzo. - In: ORGANIC LETTERS. - ISSN 1523-7060. - STAMPA. - 22:18(2020), pp. 7129-7134. [10.1021/acs.orglett.0c02471]
Synthesis of Sulfinamidines and Sulfinimidate Esters by Transfer of Nitrogen to Sulfenamides
Romanazzi, Giuseppe;
2020-01-01
Abstract
In this work we report a new synthetic tactic for the straightforward preparation of hardly accessible sulfinamidines and sulfinamide esters, by using a simple metal-free protocol. The process is robust and uses readily available sulfenamides as the S-donor and sulfonyloxycarbamates as the N-source. The scope and mechanism have also been investigated.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
