Here we report on a study of the non-radiative relaxation dynamic of 12CH4 and 13CH4 in wet nitrogen-based matrixes by using the quartz-enhanced photoacoustic spectroscopy (QEPAS) technique. The dependence of the QEPAS signal on pressure at fixed matrix composition and on H2O concentration at fixed pressure was investigated. We demonstrated that QEPAS measurements can be used to retrieve both the effective relaxation rate in the matrix, and the V-T relaxation rate associated to collisions with nitrogen and water vapor. No significant differences in measured relaxation rates were observed between the two isotopologues.
Assessment of vibrational-translational relaxation dynamics of in a wet-nitrogen matrix through QEPAS / Olivieri, Mariagrazia; Giglio, Marilena; Dello Russo, Stefano; Menduni, Giansergio; Zifarelli, Andrea; Patimisco, Pietro; Sampaolo, Angelo; Wu, Hongpeng; Dong, Lei; Spagnolo, Vincenzo. - In: PHOTOACOUSTICS. - ISSN 2213-5979. - ELETTRONICO. - 31:(2023). [10.1016/j.pacs.2023.100518]
Assessment of vibrational-translational relaxation dynamics of in a wet-nitrogen matrix through QEPAS
Giglio, Marilena;Menduni, Giansergio;Zifarelli, Andrea;Patimisco, Pietro;Sampaolo, Angelo;Spagnolo, Vincenzo
2023-01-01
Abstract
Here we report on a study of the non-radiative relaxation dynamic of 12CH4 and 13CH4 in wet nitrogen-based matrixes by using the quartz-enhanced photoacoustic spectroscopy (QEPAS) technique. The dependence of the QEPAS signal on pressure at fixed matrix composition and on H2O concentration at fixed pressure was investigated. We demonstrated that QEPAS measurements can be used to retrieve both the effective relaxation rate in the matrix, and the V-T relaxation rate associated to collisions with nitrogen and water vapor. No significant differences in measured relaxation rates were observed between the two isotopologues.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
