N-Allylani1ine (aa) upon reaction with Pd(II) and Pt(II) undergoes at room temperature in polar solvents C-N bond cleavage affording essentially aniline and methyl acetylene (small amounts of allene, ca <1%, being also formed). At higher temperatures (ca 90 °C) in absence of solvent intermo1 ecu I ar hydrogen transfer reaction takes place promoted by Pd(11) and N-allylide-neaniline and N-n-propyl ani1ine are formed. N, N-a 1 ly 1 methylaniline (maa) undergoes’ C3 unit elimination easier than (aa).
Metal Complexes with Allylanilines. II. Rearrangement of the Ligands N-Allylaniline, N,N-Allylmethylaniline, 2-Allylaniline Promoted by Co-ordination to Pd(II) and Pt(II) / Aresta, Michele; Greco, Raffaele; Petruzzelli, Domenico. - In: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY. - ISSN 0094-5714. - STAMPA. - 9:2(1979), pp. 157-174. [10.1080/00945717908059262]
Metal Complexes with Allylanilines. II. Rearrangement of the Ligands N-Allylaniline, N,N-Allylmethylaniline, 2-Allylaniline Promoted by Co-ordination to Pd(II) and Pt(II)
Domenico Petruzzelli
1979-01-01
Abstract
N-Allylani1ine (aa) upon reaction with Pd(II) and Pt(II) undergoes at room temperature in polar solvents C-N bond cleavage affording essentially aniline and methyl acetylene (small amounts of allene, ca <1%, being also formed). At higher temperatures (ca 90 °C) in absence of solvent intermo1 ecu I ar hydrogen transfer reaction takes place promoted by Pd(11) and N-allylide-neaniline and N-n-propyl ani1ine are formed. N, N-a 1 ly 1 methylaniline (maa) undergoes’ C3 unit elimination easier than (aa).I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
