This work deals with the catalytic conversion of benzyl alcohols to aldehydes or ketones using a polymer supported palladium catalyst which formed metal nanoparticles under reaction condition. The oxidation reaction was carried out on a series of substituted benzylic alcohols under air in water. The obtained results showed high selectivity also for the oxidation of primary alcohols to aldehydes without over-oxidation products. In addition, the catalyst was recycled several times with negligible metal leaching into solution.
Oxidation of Benzyl Alcohols to Aldehydes and Ketones Under Air in Water Using a Polymer Supported Palladium Catalyst / Dell’Anna, M. M.; Mali, M.; Mastrorilli, P.; Cotugno, P.; Monopoli, A.. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - STAMPA. - 386:(2014), pp. 114-119. [10.1016/j.molcata.2014.02.001]
Oxidation of Benzyl Alcohols to Aldehydes and Ketones Under Air in Water Using a Polymer Supported Palladium Catalyst
Dell’Anna, M. M.;Mali, M.;Mastrorilli, P.;Monopoli, A.
2014-01-01
Abstract
This work deals with the catalytic conversion of benzyl alcohols to aldehydes or ketones using a polymer supported palladium catalyst which formed metal nanoparticles under reaction condition. The oxidation reaction was carried out on a series of substituted benzylic alcohols under air in water. The obtained results showed high selectivity also for the oxidation of primary alcohols to aldehydes without over-oxidation products. In addition, the catalyst was recycled several times with negligible metal leaching into solution.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
