The catalytic system made up of cobalt(II) acetylacetonate, 2-methylpropanal and dioxygen (or air) facilitated the oxidative cleavage of (1S,2S,3R,5S)-(+)-pinanediol 1a and (1R,2R,3S,5R)-(−)-pinanediol 1b to enantiomerically pure cis-pinonic acids 4a–b.
Aerobic oxidative cleavage of pinanediols by cobalt(II) acetylacetonate in the presence of 2-methylpropanal / Mastrorilli, Piero; Suranna, Gian Paolo; Nobile, Cosimo Francesco; Farinola, Gianluca; Lopez, Luigi. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - STAMPA. - 156:1-2(2000), pp. 279-281. [10.1016/S1381-1169(00)00077-7]
Aerobic oxidative cleavage of pinanediols by cobalt(II) acetylacetonate in the presence of 2-methylpropanal
Piero Mastrorilli;Gian Paolo Suranna;Cosimo Francesco Nobile;
2000-01-01
Abstract
The catalytic system made up of cobalt(II) acetylacetonate, 2-methylpropanal and dioxygen (or air) facilitated the oxidative cleavage of (1S,2S,3R,5S)-(+)-pinanediol 1a and (1R,2R,3S,5R)-(−)-pinanediol 1b to enantiomerically pure cis-pinonic acids 4a–b.File in questo prodotto:
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