Dynamic processes involving the P-4 cage coordinated to transition metal fragments were observed for the mononuclear complex trans-[Ru(dppm)(2)(H)(eta(1)-P-4)]BF4 and for the bimetallic derivative trans-[Ru(dppm)(2)(H)(mu,eta(1:2)-P-4){Pt(PPh3)(2)}]BF4 as demonstrated by NMR experiments and DFT calculations
Dynamic behaviour of Ru and Ru–Pt complexes containing tetrahedro-P4 ligand
GALLO, Vito;LATRONICO, Mario;MASTRORILLI, Pietro;
2011-01-01
Abstract
Dynamic processes involving the P-4 cage coordinated to transition metal fragments were observed for the mononuclear complex trans-[Ru(dppm)(2)(H)(eta(1)-P-4)]BF4 and for the bimetallic derivative trans-[Ru(dppm)(2)(H)(mu,eta(1:2)-P-4){Pt(PPh3)(2)}]BF4 as demonstrated by NMR experiments and DFT calculationsFile in questo prodotto:
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