The E-isomer of the title substrate has been hydrogenated with 75% selectivity to the corresponding Z, E-diene at 4.5 bar H-2 and room temperature in the presence of catalytic amounts of a polymer bound rhodium complex.
Hydrogenation of ethyl 12-trimethylsilyl-9-dodecyn-11-enoate by isocyanide polymer-bound Rh(PPh3)3Cl / Fiandanese, Vito; Mastrorilli, Piero; Nobile, Cosimo Francesco; Punzi, Angela. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - STAMPA. - 136:2(1998), pp. 111-114. [10.1016/S1381-1169(98)00057-0]
Hydrogenation of ethyl 12-trimethylsilyl-9-dodecyn-11-enoate by isocyanide polymer-bound Rh(PPh3)3Cl
Piero Mastrorilli;Nobile, Cosimo Francesco;
1998-01-01
Abstract
The E-isomer of the title substrate has been hydrogenated with 75% selectivity to the corresponding Z, E-diene at 4.5 bar H-2 and room temperature in the presence of catalytic amounts of a polymer bound rhodium complex.File in questo prodotto:
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