The use of biomethane as fuel in the transport and power generation sectors is widely considered an effective tool to pursue the goals of carbon neutrality and energy security. Therefore, it is very important to promote not only the production and upgrading processes of biomethane from carbon neutral biomass, but also biomethane liquefaction processes, which can allow effective transportation of biomethane, thanks to the fact that the density of the liquid is higher than that of the compressed gas. Biomethane liquefaction plants can benefit from the technologies already used for the liquefaction of natural gas, but the size of biomethane liquefaction plants must be significantly smaller because of the limited quantities of biomethane generated by production and upgrading plants. Biomethane liquefaction plants have still limited diffusion; the most used technologies for the biomethane liquefaction are the Reverse Brayton cycle, the Lynde cycle, and the heat exchange with liquid Nitrogen. Single mixed refrigerant (SMR) processes, which are very effective for the liquefaction of natural gas, have a high potential for the biomethane liquefaction too, but the high specific energy consumption and high plant costs (mainly caused by typical multi-flow heat exchangers employed) are the major issues associated with SMR processes when applied to the very small size of biomethane liquefaction plants, characterised by very low biomethane flow rates. The aim of this paper is to propose a novel SMR process for biomethane liquefaction, which can overcome the above-mentioned issues, contributing towards the implementation of SMR processes for the liquefaction of biomethane and providing a valid alternative to currently used biomethane liquefaction plants; the proposed solution consists in using simple pipe-in-pipe heat exchangers in place of the more complex multi-flow heat exchangers. The validity of this solution is theoretically assessed using a detailed thermodynamic model based on well-stablished equations. Using this tool, it is shown that, by adjusting crucial parameters, such as the molar composition of the refrigerant, the heat exchange is satisfied with an affordable length of the heat exchangers, negligible pressure drops and good levels of the coefficient of performance with reference to such a small-scale application. The predicted specific energy consumption (accounting also for the biomethane compression and pre-cooling) for a biomethane flow rate of 0.03 kg/s is of the order of 0.8 kWh/kgCH4, which is a very good performance level compared to current commercial biomethane liquefaction processes.
A novel small-scale biomethane liquefaction process: Assessment through a detailed theoretical analysis / Tamburrano, P.; Distaso, E.; Salvatori, M.; Fedele, M.; Meschia, M.; Amirante, R.. - In: APPLIED THERMAL ENGINEERING. - ISSN 1359-4311. - 233:(2023). [10.1016/j.applthermaleng.2023.121145]
A novel small-scale biomethane liquefaction process: Assessment through a detailed theoretical analysis
Tamburrano P.
;Distaso E.;Amirante R.
2023-01-01
Abstract
The use of biomethane as fuel in the transport and power generation sectors is widely considered an effective tool to pursue the goals of carbon neutrality and energy security. Therefore, it is very important to promote not only the production and upgrading processes of biomethane from carbon neutral biomass, but also biomethane liquefaction processes, which can allow effective transportation of biomethane, thanks to the fact that the density of the liquid is higher than that of the compressed gas. Biomethane liquefaction plants can benefit from the technologies already used for the liquefaction of natural gas, but the size of biomethane liquefaction plants must be significantly smaller because of the limited quantities of biomethane generated by production and upgrading plants. Biomethane liquefaction plants have still limited diffusion; the most used technologies for the biomethane liquefaction are the Reverse Brayton cycle, the Lynde cycle, and the heat exchange with liquid Nitrogen. Single mixed refrigerant (SMR) processes, which are very effective for the liquefaction of natural gas, have a high potential for the biomethane liquefaction too, but the high specific energy consumption and high plant costs (mainly caused by typical multi-flow heat exchangers employed) are the major issues associated with SMR processes when applied to the very small size of biomethane liquefaction plants, characterised by very low biomethane flow rates. The aim of this paper is to propose a novel SMR process for biomethane liquefaction, which can overcome the above-mentioned issues, contributing towards the implementation of SMR processes for the liquefaction of biomethane and providing a valid alternative to currently used biomethane liquefaction plants; the proposed solution consists in using simple pipe-in-pipe heat exchangers in place of the more complex multi-flow heat exchangers. The validity of this solution is theoretically assessed using a detailed thermodynamic model based on well-stablished equations. Using this tool, it is shown that, by adjusting crucial parameters, such as the molar composition of the refrigerant, the heat exchange is satisfied with an affordable length of the heat exchangers, negligible pressure drops and good levels of the coefficient of performance with reference to such a small-scale application. The predicted specific energy consumption (accounting also for the biomethane compression and pre-cooling) for a biomethane flow rate of 0.03 kg/s is of the order of 0.8 kWh/kgCH4, which is a very good performance level compared to current commercial biomethane liquefaction processes.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
