Peculiar hindered olefins and derivatives have been epoxidized, under Mukaiyama's conditions, using iron(III) catalytic centres. The experimental results allow to rule out the involvement of singlet oxygen and free peroxyacids as active species.
Aerobic epoxidation of hindered olefins and enol ethers catalyzed by a polymerizable β-ketoesterate complex of iron(III) / Lopez, Luigi; Mastrorilli, Piero; Mele, Giuseppe; Nobile, Cosimo F.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 35:21(1994), pp. 3633-3636. [10.1016/S0040-4039(00)73259-X]
Aerobic epoxidation of hindered olefins and enol ethers catalyzed by a polymerizable β-ketoesterate complex of iron(III)
Piero Mastrorilli;Cosimo F. Nobile
1994-01-01
Abstract
Peculiar hindered olefins and derivatives have been epoxidized, under Mukaiyama's conditions, using iron(III) catalytic centres. The experimental results allow to rule out the involvement of singlet oxygen and free peroxyacids as active species.File in questo prodotto:
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