The addition of β-dioxygenato compounds to methyl vinyl ketone was catalysed by nickel (II) and cobalt (II) complexes with the polymerizable β-ketoesterato 2-(acetoacetoxy)ethyl methacrylate (AAEMA−) under homogeneous and heterogeneous phases. The homogeneous reactions were carried out using the soluble Ni(AAEMA)2 and Co(AAEMA)2 complexes whereas the heterogeneous catalytic tests were carried out using the copolymers obtained by reaction of M(AAEMA)2 (M Ni or Co) with suitable acrylamides.
Catalytic activity of polymerizable metal β-ketoesterato complexes towards Michael addition reactions / Mastrorilli, P.; Nobile, C. F.; Suranna, G. P.. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - STAMPA. - 103:1(1995), pp. 23-29. [10.1016/1381-1169(95)00095-X]
Catalytic activity of polymerizable metal β-ketoesterato complexes towards Michael addition reactions
P. Mastrorilli;C. F. Nobile;G. P. Suranna
1995-01-01
Abstract
The addition of β-dioxygenato compounds to methyl vinyl ketone was catalysed by nickel (II) and cobalt (II) complexes with the polymerizable β-ketoesterato 2-(acetoacetoxy)ethyl methacrylate (AAEMA−) under homogeneous and heterogeneous phases. The homogeneous reactions were carried out using the soluble Ni(AAEMA)2 and Co(AAEMA)2 complexes whereas the heterogeneous catalytic tests were carried out using the copolymers obtained by reaction of M(AAEMA)2 (M Ni or Co) with suitable acrylamides.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
