The addition of β-dioxygenato compounds to methyl vinyl ketone was catalysed by nickel (II) and cobalt (II) complexes with the polymerizable β-ketoesterato 2-(acetoacetoxy)ethyl methacrylate (AAEMA−) under homogeneous and heterogeneous phases. The homogeneous reactions were carried out using the soluble Ni(AAEMA)2 and Co(AAEMA)2 complexes whereas the heterogeneous catalytic tests were carried out using the copolymers obtained by reaction of M(AAEMA)2 (M Ni or Co) with suitable acrylamides.
|Titolo:||Catalytic activity of polymerizable metal β-ketoesterato complexes towards Michael addition reactions|
|Data di pubblicazione:||1995|
|Digital Object Identifier (DOI):||10.1016/1381-1169(95)00095-X|
|Appare nelle tipologie:||1.1 Articolo in rivista|