The oxidation of benzylic and secondary alcohols under homogeneous conditions was achieved at 40°C using molecular oxygen as the oxidant in the presence of excess 2-methylpropanal and catalytic amount of Co(acac)2. The oxidation reactions were also carried out with a heterogeneous analogue of Co(acac)2 revealing that the supported cobalt polymer acts as an active and reusable catalyst.
|Titolo:||Homogeneous and heterogeneous catalytic oxidation of benzylic and secondary alcohols with a metal dioxygenato complex in the presence of 2-methylpropanal and dioxygen|
|Data di pubblicazione:||2001|
|Digital Object Identifier (DOI):||10.1016/S1381-1169(00)00370-8|
|Appare nelle tipologie:||1.1 Articolo in rivista|