We present a robust and cost-effective coating method to fabricate long-term durable superhydrophobic and - simultaneously - antireflective surfaces by a double-layer coating comprising trimethylsiloxane (TMS) surface-functionalized silica nanoparticles partially embedded into an organosilica binder matrix produced through a sol-gel process. A dense and homogeneous organosilica gel layer was first coated onto a glass substrate, and then, a trimethylsilanized nanospheres-based superhydrophobic layer was deposited onto it. After thermal curing, the two layers turned into a monolithic film, and the hydrophobic nanoparticles were permanently fixed to the glass substrate. Such treated surfaces showed a tremendous water repellency (contact angle = 168°) and stable self-cleaning effect during 2000 h of outdoor exposure. Besides this, nanotextured topology generated by the self-assembled nanoparticles-based top layer produced a fair antireflection effect consisting of more than a 3% increase in optical transmittance. © 2009 American Chemical Society.

Durable superhydrophobic and antireflective surfaces by trimethylsilanized silica nanoparticles-based sol-gel processing / Manca, Michele; Cannavale, Alessandro; De Marco, Luisa; Aricò, Antonino S.; Cingolani, Roberto; Gigli, Giuseppe. - In: LANGMUIR. - ISSN 0743-7463. - STAMPA. - 25:11(2009), pp. 6357-6362. [10.1021/la804166t]

Durable superhydrophobic and antireflective surfaces by trimethylsilanized silica nanoparticles-based sol-gel processing

Cannavale, Alessandro;
2009-01-01

Abstract

We present a robust and cost-effective coating method to fabricate long-term durable superhydrophobic and - simultaneously - antireflective surfaces by a double-layer coating comprising trimethylsiloxane (TMS) surface-functionalized silica nanoparticles partially embedded into an organosilica binder matrix produced through a sol-gel process. A dense and homogeneous organosilica gel layer was first coated onto a glass substrate, and then, a trimethylsilanized nanospheres-based superhydrophobic layer was deposited onto it. After thermal curing, the two layers turned into a monolithic film, and the hydrophobic nanoparticles were permanently fixed to the glass substrate. Such treated surfaces showed a tremendous water repellency (contact angle = 168°) and stable self-cleaning effect during 2000 h of outdoor exposure. Besides this, nanotextured topology generated by the self-assembled nanoparticles-based top layer produced a fair antireflection effect consisting of more than a 3% increase in optical transmittance. © 2009 American Chemical Society.
2009
http://pubs.acs.org/doi/pdfplus/10.1021/la804166t
Durable superhydrophobic and antireflective surfaces by trimethylsilanized silica nanoparticles-based sol-gel processing / Manca, Michele; Cannavale, Alessandro; De Marco, Luisa; Aricò, Antonino S.; Cingolani, Roberto; Gigli, Giuseppe. - In: LANGMUIR. - ISSN 0743-7463. - STAMPA. - 25:11(2009), pp. 6357-6362. [10.1021/la804166t]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11589/82516
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