The reaction between Ni(0) complexes (dp) (dp = 1,2-bis(dicyclohexylphosphino)ethane, 1,3-bis(dicyclohexylphosphino)propane, 1,4-bis(dicyclohexylphosphino)butane; dcpe, dcpp, dcpb, respectively) and carbon dioxide is described. The influence of the PNiP bond angle on the stability of the corresponding adducts is discussed. The reactions of Ni(dcpp)CO2 and Ni(dcpb)CO2 with dioxygen are also described.
|Titolo:||Carbon dioxide-transition metal complexes. IV. New Ni(0)CO2 complexes with chelating diphosphines: influence of PNiP angle on complex stabilities|
|Data di pubblicazione:||1992|
|Digital Object Identifier (DOI):||10.1016/S0020-1693(00)80758-6|
|Appare nelle tipologie:||1.1 Articolo in rivista|