This article reports the use of a cascade Suzuki–Heck reaction for the polymerization of suitable aryldibromides with potassium vinyltrifluoroborate resulting in the synthesis of a series of poly(fluorenylenevinylene)s. The protocol is characterized by a great versatility, deriving from the use of easily attainable substrates, and yields polymers with low percentages of structural 1,1-diarylenevinylene defects.
A novel synthetic protocol for poly(fluorenylenevinylene)s: a cascade Suzuki-Heck reaction / Grisorio, R.; Mastrorilli, P.; Nobile, C. F.; Romanazzi, G.; Suranna, G. P.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 46:15(2005), pp. 2555-2558. [10.1016/j.tetlet.2005.02.090]
A novel synthetic protocol for poly(fluorenylenevinylene)s: a cascade Suzuki-Heck reaction
Grisorio, R.;Mastrorilli, P.;Romanazzi, G.;Suranna, G. P.
2005-01-01
Abstract
This article reports the use of a cascade Suzuki–Heck reaction for the polymerization of suitable aryldibromides with potassium vinyltrifluoroborate resulting in the synthesis of a series of poly(fluorenylenevinylene)s. The protocol is characterized by a great versatility, deriving from the use of easily attainable substrates, and yields polymers with low percentages of structural 1,1-diarylenevinylene defects.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
