The reaction of tetraphenyldiphosphine with NiCl2 and Pd(PhCN)2Cl2 was investigated. Aquo or alcohol complexes of nickel(II) chloride afforded Ni(PPh2H)4 whereas anhydrous NiCl2 in aromatic solvents facilitated the decomposition of the diphosphine into triphenylphosphine and diphenylphosphine. Pd(PhCN)2Cl2 gave rise to Pd(Ph2P-PPh2)Cl2.
Reaction of Nickel(II) and Palladium(II) with Tetraphenyldiphosphine / Giannandrea, Roberto; Mastrorilli, Piero; Nobile, Cosimo Francesco; Dilonardo, Massimo. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 249:2(1996), pp. 237-238. [10.1016/0020-1693(96)05086-4]
Reaction of Nickel(II) and Palladium(II) with Tetraphenyldiphosphine
Piero Mastrorilli;Cosimo Francesco Nobile;Dilonardo, Massimo
1996-01-01
Abstract
The reaction of tetraphenyldiphosphine with NiCl2 and Pd(PhCN)2Cl2 was investigated. Aquo or alcohol complexes of nickel(II) chloride afforded Ni(PPh2H)4 whereas anhydrous NiCl2 in aromatic solvents facilitated the decomposition of the diphosphine into triphenylphosphine and diphenylphosphine. Pd(PhCN)2Cl2 gave rise to Pd(Ph2P-PPh2)Cl2.File in questo prodotto:
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