The reaction of tetraphenyldiphosphine with NiCl2 and Pd(PhCN)2Cl2 was investigated. Aquo or alcohol complexes of nickel(II) chloride afforded Ni(PPh2H)4 whereas anhydrous NiCl2 in aromatic solvents facilitated the decomposition of the diphosphine into triphenylphosphine and diphenylphosphine. Pd(PhCN)2Cl2 gave rise to Pd(Ph2P-PPh2)Cl2.

Reaction of Nickel(II) and Palladium(II) with Tetraphenyldiphosphine

Piero Mastrorilli;Cosimo Francesco Nobile;Dilonardo, Massimo
1996

Abstract

The reaction of tetraphenyldiphosphine with NiCl2 and Pd(PhCN)2Cl2 was investigated. Aquo or alcohol complexes of nickel(II) chloride afforded Ni(PPh2H)4 whereas anhydrous NiCl2 in aromatic solvents facilitated the decomposition of the diphosphine into triphenylphosphine and diphenylphosphine. Pd(PhCN)2Cl2 gave rise to Pd(Ph2P-PPh2)Cl2.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11589/8515
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