The reactions of [(cod)RhCl](2) (cod = 1,5-cyclooctadiene) and Na2PdCl4 with the anion of 2-(acetoacetoxy)ethyl methacrylate (AAEMA(-)) afforded (cod)Rh(AAEMA) (1) and Pd(AAEMA)(2) (2). Thermal copolymerization of 1 and 2 with suitable comonomers and cross-linkers yielded insoluble resins that have been characterised by elemental analyses, IR, UV-Vis, XPS and SEM techniques and successfully used in the hydrogenation of 1-heptene under mild conditions. (C) 2000 Elsevier Science S.A. All rights reserved.
Synthesis and copolymerization of rhodium(I) and palladium(II) complexes with the deprotonated form of 2-(acetoacetoxy)ethyl methacrylate / Dell'Anna, M. M.; Mastrorilli, P; Rizzuti, A; Suranna, Gp; Nobile, Cf. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 304:1(2000), pp. 21-25. [10.1016/S0020-1693(00)00055-4]
Synthesis and copolymerization of rhodium(I) and palladium(II) complexes with the deprotonated form of 2-(acetoacetoxy)ethyl methacrylate
Dell'Anna M. M.;Mastrorilli P;Rizzuti A;Suranna GP;Nobile CF
2000-01-01
Abstract
The reactions of [(cod)RhCl](2) (cod = 1,5-cyclooctadiene) and Na2PdCl4 with the anion of 2-(acetoacetoxy)ethyl methacrylate (AAEMA(-)) afforded (cod)Rh(AAEMA) (1) and Pd(AAEMA)(2) (2). Thermal copolymerization of 1 and 2 with suitable comonomers and cross-linkers yielded insoluble resins that have been characterised by elemental analyses, IR, UV-Vis, XPS and SEM techniques and successfully used in the hydrogenation of 1-heptene under mild conditions. (C) 2000 Elsevier Science S.A. All rights reserved.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
